Insulation, Radiant and Vapor Barriers - insulating a finished basement

Hello, my 1966 Minnesota rambler has a cold basement. The kids rooms are downstairs and they're not happy about that! The home is heated with radiant boiler baseboards, but the basement zone only works when the main level thermostadt is simultaniously calling out for heat.
What is the simplest, most effective method of insulating the exterior block walls of the basement?
Also, I'm doing some major remodelling, and my main level mudroom/ 1/2 bath, sits on an un-insulated slab. I'm planning to install Pex tubing in-floor heat in this 7'9" X 21' area after I insulate the slab. What are my options here? What is an effective thermal break that can have scredd poured directly over it after being installed over the original slab?
Thanks, Brian

I would first start with rezoning the heat for a call down on the basement demand. Are your walls below grade? If so, they are probably staying at about 72 degrees F. year round. No additional insulation would benefit you in that respect, since they are geothermally correct. But if you expect any heat in that area aside from what is called for upstairs, you will need to rezone it. Floor heating is another matter, one that I have no experience in. Others will chime in I am sure about that, however.